Effective thermal management is paramount for successfully deploying lithium-ion batteries in residential settings as storage systems for the exploitation of renewable sources. Uncontrolled temperature increases within battery packs can lead to critical issues such as cell overheating, potentially culminating in thermal runaway events and, in extreme cases, leading to fire or explosions. This work presents a comprehensive numerical thermal model of a battery pack made of prototype pouch cells based on lithium ferrophosphate (LFP) chemistry. The multi-physical model is specifically developed to investigate real-world operating scenarios and to assess safety considerations. The considered energy storage system is a battery designed for residential applications, in its integration with a photovoltaic (PV) installation. The actual electrochemical behavior of the prototype cell during the charging and discharging processes is modeled and validated on the ground of experimental data. The essential steps leading to the numerical schematization of the battery pack are then presented to apply the model to two different use scenarios, differing for the user loads. The work provides an essential foundation for conducting numerical simulations of battery packs operating also at higher power levels.
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